List all NM connections:
$ nmcli con
Start connection (wifi, vpn, etc)
$ nmcli con up id ConnectionName
Stop connection:
$ nmcli con down id ConnectionName

Technical notes, and other ideas.
List all NM connections:
$ nmcli con
Start connection (wifi, vpn, etc)
$ nmcli con up id ConnectionName
Stop connection:
$ nmcli con down id ConnectionName